EHS glossary>Safety term

The Definition of Oxidizer

An oxidizer is a chemical that supplies oxygen or otherwise causes or intensifies the burning of other materials, such as peroxides, nitrates and chlorates.

Plain-English definition
Real-world example
Oxidizer definition card

Definition of Oxidizer

An oxidizer is a substance that can cause or intensify the combustion of other materials, usually by giving up oxygen. Oxidizers don't always burn themselves, but when they contact fuels, organic materials or other incompatible chemicals, they can start fires, make fires burn hotter and faster, or cause explosions. Common workplace oxidizers include hydrogen peroxide, nitric acid, ammonium nitrate, sodium hypochlorite, potassium permanganate, chlorates, perchlorates and compressed oxygen.

Key Facts About Oxidizers

  • Under the GHS, oxidizing gases, liquids and solids are labeled with the flame-over-circle pictogram.
  • The U.S. DOT classifies oxidizers as Hazard Class 5.1 and organic peroxides as Class 5.2.
  • NFPA 400 sets storage and handling requirements for oxidizer solids and liquids by hazard class.
  • Oxygen-enriched atmospheres, above 23.5 percent oxygen in confined spaces, make materials ignite more easily and burn more intensely.
  • Oil and grease must never be used on oxygen fittings or regulators.

Example of an Oxidizer

A water treatment plant stores sodium hypochlorite in a dedicated, bermed area away from acids and organic materials. When a contractor proposes storing absorbent pads and fuel containers nearby, the safety manager blocks it because of the fire and reaction risk.

How to Store and Handle Oxidizers

  1. Check the safety data sheet for oxidizer hazards and incompatibilities.
  2. Store oxidizers separately from flammables, combustibles, reducing agents and acids.
  3. Keep storage areas cool, dry and away from ignition sources.
  4. Use compatible containers and clean up spills immediately with non-combustible absorbents.
  5. Train workers on segregation rules and labeling.

Related Terms

Frequently Asked Questions: Oxidizer

Is an oxidizer flammable?

Most oxidizers aren't flammable themselves, but they make other materials burn more easily and intensely, which can be just as dangerous.

What does OX mean on an NFPA 704 diamond?

OX in the white special hazards section indicates the material is an oxidizer.

Can oxidizers be stored with flammable liquids?

No. Oxidizers should be physically separated from flammable and combustible materials, typically in different cabinets or areas, to prevent fires and violent reactions.

Part of SafetyIQ's EHS glossary: plain-English definitions of workplace health and safety terms.

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