A process hazard analysis (PHA) is a systematic team review of a chemical process to identify what could go wrong, the consequences and whether safeguards are adequate.

A process hazard analysis (PHA) is a structured, team-based review of a process that handles hazardous chemicals. It identifies potential deviations and failures, such as loss of cooling, overpressure or a leak, evaluates their causes and consequences and judges whether existing safeguards are adequate. The output is a set of recommendations to reduce risk.
Under OSHA's Process Safety Management standard, 29 CFR 1910.119(e), a PHA is required for covered processes, must be performed by a team that includes engineering and operating expertise and at least one person who knows the PHA method being used, and must be updated and revalidated at least every five years.
During a HAZOP of an ammonia refrigeration system, the team considers "more pressure" in a receiver. They find that a single relief valve vents to a location near an occupied building, so they recommend rerouting the discharge and adding a high-pressure alarm.
A HAZOP is one method of performing a PHA. PHA is the broader requirement, and teams can choose HAZOP, what-if, checklist or other recognized methods.
At least every five years under OSHA PSM, and sooner if significant changes or incidents warrant it.
Engineers, experienced operators, maintenance staff and a facilitator skilled in the method. Including operators is essential because they know how the process really runs.
Part of SafetyIQ's EHS glossary: plain-English definitions of workplace health and safety terms.
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